So, some help/ideas please guys as to how to sort this

Bit of background - The Lexia was bought from a reputable (FCF recommended) seller and I've successfully used my Lexia to talk to 2x Mk1 c5's. My Activa has previously refused to talk to 3 different after-market diagnostic tools (of varying expense - not mine, but mobile diagnostic techs).
I'm suspicious therefore that it's the car that's the problem, not the Lexia. However, talking to the Activa does of course use an extra connector that the C5 doesn't need...
A few pics:
Connectors galore;

Clip removed, so the plug goes properly home;

Tried connecting by automatic detection and manual.
Automatic;





Manual;




I also tried it starting with ignition off and only turning it on when told and also with the ignition on. No difference in how it proceeds.
Into Lexia;

Global test;


Dutifully followed instruction;

Results;


Went into the injection ECU and picked the right option;



Same for ABS;

Suspension...;

Even tried the firmware writing option;





I also tried Scantool (never used this before, so no idea what it actually does, but whatever!)




FWIW, some of the setup information for the tool;

Serial number of tool;

(I have screen dumps of the extra info as well if anyone wants to see, e.g.)

Soooo... Any thoughts please people?
Or anyone with a Lexia that they know talks to S1 Xantia's that can pop round by any chance?