Thanks to the above discussion (all the detail in that thread) I have got Lexia talking to the car (partially).
First result was this;



Anyway, I ploughed on going into the injection diagnostics;


Yes, well done, that's my car

Identification;

Interesting...

Read faults;


Into this then, to see if that sheds any light;




I've no data to go on, but I thought the ignition advance looked a bit excessive?
Anyway, the screen then crashed out (said connection to ECU lost).
Next up, to run through the test options it gives you (limited on this ECU)...


Great

Nothing worked from then on. I rebooted Lexia, turned the car off and on, no change.
Wiggled the leads around where they connect into the PCI unit and found the RS232 plug ever so slightly loose... Tightened it up et voila!
Suddenly we have logged faults!


And the best thing? It confirmed my suspicion all along that it was probably a knock sensor fault!

Anyway, I ran through the rest of the tests;


All checked out ok. The injectors are really quiet though, took a lot of very careful listening - I was sure one wasn't working, so resistance checked them (all ok at 16ohm) and re-tested several times before I managed to hear the last one (difficult to get ear close up to that particular one).
So... Knock sensor. Difficult thing to test. All the wiring visibly looks intact. I'll bell it out back to the injection ECU and if that's ok, change the sensor. Hopefully that will be the end of it...