Yes a petrol engine will chuck out quite a bit more HC and CO when the cat is cold than when it is hot. Especially when started completely from cold because the mixture will be enriched, which means enough HC to smell on some cars... If the engine is already hot from recent driving and only the cat has to warm up the situation is not as bad as it will not be running at a rich mixture.Paul-R wrote: ↑18 Nov 2017, 10:52 Nobody to my knowledge has seriously questioned a petrol engine's real life emissions. There does seem to be a concerted effort by parties with an axe to grind against diesel powered vehicles. I would be willing to bet that a petrol engine chucks out more nasties than it's supposed to especially when it's cold and the cat isn't up to working temperature. At least on a diesel the DPF works regardless of the engine temperature.
But you're forgetting that Diesel's also have a catalytic converter which also doesn't do squat when it's cold. Diesel cats are only 2 way not 3 way, (since they're running lean burn most of the time) so it converts CO and O2 to CO2 and HC to CO2 and water.
So when a Diesel cat is cold it produces a lot more CO, which is pretty noxious stuff in confined spaces of course...and under acceleration will produce more HC when the cat is cold, and because a Diesel engine is more efficient and produces less waste heat through the exhaust, it's more difficult to heat the cat up quickly than a petrol...
The 3 way cat in a petrol car is more capable - as well as what the Diesel cat can do it can also convert NOx back to Nitrogen and Oxygen, which is one reason why the NOx on petrol engines is so low, as well as the fact that they don't produce nearly as much to begin with as they don't run lean like Diesel.
The DPF might work all the time, but it's only there to catch soot particles that properly running petrol engines (GDI excepted) don't produce in the first place.